Dislocation-based competition of plasticity and cracking in oxides: a scale-dependent study
FANG X. 1, DING K. 1, RÖDEL J. 1
1 Technische Universität Darmstadt, Darmstadt, Germany
Dislocations in ceramic oxides are drawing increasing attention owing to their promising properties, including dislocation-tuned electrical conductivity, thermal conductivity, and electro-mechanical properties as well as enhanced fracture toughness damage tolerance. However, due to the brittleness of most oxides at room temperature, it remains a great challenge to engineer dislocations without forming cracks, which is a prerequisite for harnessing these promising properties. From the aspect of mechanical deformation, nano-/micromechanical testing is a feasible approach to achieve this goal. Here, we first demonstrate that dislocations can be effectively introduced into various ceramic oxides (e.g., SrTiO3, BaTiO3, TiO2, and Al2O3) at room temperature by using nanoindentation pop-in stop tests. Interestingly, we find a size-dependent competition between purely dislocation-dominated plastic deformation under a critical indenter tip radius and a concurrent appearance of cracks and dislocations when the tip radius is larger than a certain value. We further extend the deformation scale up to the millimeter regime using Brinell indentation and identify a reversal of the above size-dependent competition. We will address the underlying mechanisms by examining the dislocation nucleation, multiplication, and motion individually to shed new light on the dislocation mechanics in oxides at room temperature.