comparative study of sliding wear without lubrication of boron carbide composites sintered by spark plasma with and without silicon auxiliaries.
ZAMORA RODRIGUEZ V. 1, MARTÍNEZ VÁZQUEZ F. 2, GUIBERTEAU CABANILLAS F. 1, ORTÍZ SECO Á. 1
1 University of Extremadura, Badajoz, Spain; 2 University of Seville, Seville, Spain
A couple of fully-dense boron carbide–silicon carbide composites were fabricated by spark-plasma sintering (SPS) from boron carbide + silicon powders, one superhard (i.e., ~28.7(8) GPa) with more than enoguh silicon carbide by SPS of boron carbide + 20vol.% silicon at 1400°C and the other ultrahard (i.e., ~35.1(4) GPa) with little silicon carbide by SPS of boron carbide + 4.28vol.% silicon at 1800°C, and their unlubricated sliding wear was examined and weighted with those of the reference boron carbide monoliths. It was discovered that the two boron-silicon carbide composites endured mild tribo-oxidative wear with preferential removal of the oxide tribolayer, with the one SPS-ed at 1400°C from boron carbide + 20vol.% silicon being, despite its lower hardness and greater proneness to form oxide tribolayer, only slightly less wear resistant than the one SPS-ed at 1800°C from boron carbide + 4.28vol.% silicon (i.e., ~1.0(5)·107 vs 1.37(8)·107 (N·m)/mm³). The reference boron carbide monolith SPS-ed at 1400°C is comparatively two fold less wear resistant (i.e., ~1.70(6)·105 (N·m)/mm³), attributable to its undergoing severe purely mechanical wear by microfracture-dominated three-body abrasion due to its very poor sintering (i.e., high porosity of ~33.5%), poor grain cohesion, and low hardness (i.e., ~3.1(5) GPa). The reference boron carbide monolithc SPS-ed at 1800°C, while equally or less hard (i.e., 28.4(9) GPa) and slightly porous (i.e., ~5.3%), is somewhat more wear resistant (~1.8(3)·107 (N·m)/mm³) than the boron-silicon carbide composites, attributable to its undergoing only mild purely mechanical wear by plasticity dominated two body abrasion without porosity-induced grain pull-out, but it requires SPS temperatures well above 1400°C.