Spark Plasma Sintering of boron carbide with metal disilicides
OJALVO C. 1, ZAMORA V. 1, GUIBERTEAU F. 1, ORTIZ Á. 1
1 Department of Mechanical, Energy and Materials Engineering, University of Extremadura, 06006, Badajoz, Spain
The densification of B4C by spark plasma sintering (SPS) with metal disilicides (MeSi2) is explored. It is identified that MeSi2 acts as a reactive sintering additive, forming in-situ SiC, the corresponding metal diboride (MeB2), and Si, and that this latter promotes densification by transient liquid phase sintering with greater formation of SiC. The densifiability is studied as a function of the increasing proportion of MeSi2 aids, demonstrating that a broad spectrum of full-dense B4C–MeB2–SiC composites can be obtained at increasingly lower SPS temperatures. Finally, it is shown that these B4C–MeB2–SiC composites have fine-grained microstructures and that they are superhard and tougher than monolithic B4C ceramics, which together with their easier fabricability makes them very appealing for structural applications.